>Roy said "As it empties, the
>pressure of the bottle is
>much less than the atmospheric
>pressure"
>
>So if the pressure of the
>bottle is much less than
>the atmospheric pressure, please explain
>how the propane comes out
>of the open valve rather
>than the atmosphere going into
>the tank. What you
>just described is what is
>referred to in the scientific
>community as a vacuum in
>a bottle.
"Propane has exellent refrige properties. If propane sits in a propane bottle the pressure of the bottle will be the vapor pressure of the propane thats in the bottle. Consumer spec propane actually has 5% ethane in it. Since propane is heavier then ethane, the more ethane in the propane the higher the vapor pressure the bottle will have. The hotter the ambient temperature is the more the lighter carbons inside the bottle will be in vapor form creating more vapor pressure and visa-versa if its cold. Sometime when it is -20 degrees, the propane will not have enough pressure to leave the bottle if there isn't enough ethane in the product.
As you use propane out of a bottle, the vapor pressure of the bottle is being reduced causing the propane to flash back to the vapor pressure of the product and cooling the metal at the mixed phase point inside the bottle. Where the metal is the coldest, the ambient dew point (the point at which the moisture in the air will turn to a solid) will condence on the bottle and since water freezes at 32 degrees it causes the dew to freeze. As the amount of propane in the bottle reduces, the more the propane has to flash to get to the vapor pressure of the product and since the ethane is lighter, all the ethane will have been used before all the propane. Thats why the frost usually accures when the bottle level is low."
This.
I just explained it in a far less complex way. Sorry if I over-simplified it, but the same principle applies. Only at extreme temperatures and atmospheric conditions would you get the "vacuum in a bottle" effect you are describing.
Oh, and I wouldn't be going around bragging that you are a member of "the scientific community" if I were you Bigfoot46, at least not around actual members of "the scientific community".
HOOK 'EM!
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